2.1. Gas relative density (d) equal relative density (ρ1 and ρ2) gases (under the same pressure and temperature):
d = ρ1: ρ2 ≈ M1 :M2 (2.1)
where m1 and m2 -molecular mass of gases.
Relative density of gas:
in relation to the air: d ≈ m/29
in relation to hydrogen: d ≈ m/2
where m, 29 and 2 -the molecular mass of the gas, air and hydrogen.
2.2. Weighted number of and (in g ) gas in this volume V (in DM3):
- a = m *1.293 *g *273 * V /28.98 (273 +t) *760 = 0.01605 * r * m * V/273 + t (2.2)
where m is the molecular weight of the gas, r-gas pressure, mm Hg., t is the temperature of the gas, 0With.
The amount of gas in grams per 1 DM3 under normal conditions
a = 1,293 : d
where d is the relative density of gas in relation to air.
2.3. Volume V, occupied by the data sender number and strip:
V = a * 13.9 *760*(273 +t) /M * r (2.4)
2.5. Gas mixtures
Weight (in g) mix n shaped components, with volume V1, V2 … (V)n and molecular mass m1, M2 … Mn, equal
where 22,4 -volume 1 a mole of a substance in gaseous state at 273 To and 101,32 kPa (0° C and 760 mm. RT. article)
As the volume of the mixture of V = V1 + V2 + ... + Vn, it 1 DM3 It has a lot of:
The average molecular mass m of gas mixture (When additivity properties) equal:
The concentration of the gas mixture components expressed most often in volume percentage. Concentration (V1/V·100) numerically matches with a fraction of the partial pressure of component (g1/g·100) and with its mol′noj concentration (M1/M·100).
Shares of individual components (i) in a gas mixture is equal, %
mass volumetric
where qi -mass content of component i in the mixture.
In equal volumes of different gases under identical conditions contain equal numbers of molecules, so
g1:g2: … = V1:V2: … = М1:M2:...
where m is the number of moles of.
The number of moles of a component:
etc.
If gas is in some circumstances (P, T) and it is necessary to determine its volume or mass of other conditions (R ´, T ´), use formulas:
to recalculate the amount of
for the calculation of the mass
At t = const partial pressure Pus saturated steam in a gas mixture regardless of total pressure constantly. When 101,32 KPA and t k 1 a mole of gas or vapor occupies a volume of 22,4 (T/273)DM3. If the vapor pressure at that temperature is equal to rus, the volume of 1 Mole is equal to:
Thus, weight of 1m3 a pair of molecular mass m at a temperature t and pressure pus equal, in the g/m3
Knowing the mass content of saturated steam at 1 m3 mix, You can calculate its pressure:
Dry gas volume calculate by the formula:
where rus, t -pressure saturated steam at temperature t.
Cast dry volume V(T,P)Suh. and humid V(T,P)VL. gases to normal conditions (n.u.) (273 To and 101,32 kPa) produce formulas:
Formula
use to recalculate the amount of wet gas, in the r and t, other r ´, T ´, provided, that with the change of temperature changes and the equilibrium vapour pressure. The expression for the calculation of the volume of gas in various conditions similar to:
If the pressure of the water vapour saturated steam at any temperature is equal to rus., and you must calculate Gn.. -the content of it in 1 m3 gas n.a., use the equation (1.2), but in this case there is no saturation temperature t, and equal 273 To.
It follows, what:
Gn.. = 4,396·10-7 Mrus..
Pressure saturated steam, If you know its contents in 1 m3 When Mr.. calculate using the formula: